AFAIK，无法通过纯XML做到这一点。无论如何，这是我今天早上做的一些代码：

一，测试：

public class EnvironmentTests {

    @Test
    public void addPropertiesToEnvironmentTest() {

        ApplicationContext context = new ClassPathXmlApplicationContext(
                "testContext.xml");

        Environment environment = context.getEnvironment();

        String world = environment.getProperty("hello");

        assertNotNull(world);

        assertEquals("world", world);

        System.out.println("Hello " + world);

    }

}

然后上课：

public class PropertySourcesAdderBean implements InitializingBean,
        ApplicationContextAware {

    private Properties properties;

    private ApplicationContext applicationContext;

    public PropertySourcesAdderBean() {

    }

    public void afterPropertiesSet() throws Exception {

    PropertiesPropertySource propertySource = new PropertiesPropertySource(
            "helloWorldProps", this.properties);

    ConfigurableEnvironment environment = (ConfigurableEnvironment) this.applicationContext
            .getEnvironment();

    environment.getPropertySources().addFirst(propertySource);

    }

    public Properties getProperties() {
        return properties;
    }

    public void setProperties(Properties properties) {
        this.properties = properties;
    }

    public void setApplicationContext(ApplicationContext applicationContext)
            throws BeansException {

        this.applicationContext = applicationContext;

    }

}

和testContext.xml：

<?xml version="1.0" encoding="UTF-8"?>
<beans ...>

    <util:properties id="props" location="classpath:props.properties" />

    <bean id="propertySources" class="org.mael.stackoverflow.testing.PropertySourcesAdderBean">
        <property name="properties" ref="props" />
    </bean>


</beans>

和props.properties文件：

hello=world

这是很简单，只需使用一个ApplicationContextAwarebean并获得ConfigurableEnvironment从(Web)ApplicationContext。然后只需PropertiesPropertySource在MutablePropertySources