下面的函数GetCharFromKey（Key key）可以解决问题。

它使用一系列win32调用来解码按下的键：

1. 从WPF密钥获取虚拟密钥

2. 从虚拟密钥获取扫描代码

3. 得到你的Unicode字符

这篇旧文章对此进行了更详细的描述。

      public enum MapType : uint
      {
         MAPVK_VK_TO_VSC = 0x0,
         MAPVK_VSC_TO_VK = 0x1,
         MAPVK_VK_TO_CHAR = 0x2,
         MAPVK_VSC_TO_VK_EX = 0x3,
      }

      [DllImport("user32.dll")]
      public static extern int ToUnicode(
          uint wVirtKey,
          uint wScanCode,
          byte[] lpKeyState,
          [Out, MarshalAs(UnmanagedType.LPWStr, SizeParamIndex = 4)] 
            StringBuilder pwszBuff,
          int cchBuff,
          uint wFlags);

      [DllImport("user32.dll")]
      public static extern bool GetKeyboardState(byte[] lpKeyState);

      [DllImport("user32.dll")]
      public static extern uint MapVirtualKey(uint uCode, MapType uMapType);

      public static char GetCharFromKey(Key key)
      {
         char ch = ' ';

         int virtualKey = KeyInterop.VirtualKeyFromKey(key);
         byte[] keyboardState = new byte[256];
         GetKeyboardState(keyboardState);

         uint scanCode = MapVirtualKey((uint)virtualKey, MapType.MAPVK_VK_TO_VSC);
         StringBuilder stringBuilder = new StringBuilder(2);

         int result = ToUnicode((uint)virtualKey, scanCode, keyboardState, stringBuilder, stringBuilder.Capacity, 0);
         switch (result)
         {
            case -1: 
               break;
            case 0: 
               break;
            case 1:
               {
                  ch = stringBuilder[0];
                  break;
               }
            default:
               {
                  ch = stringBuilder[0];
                  break;
               }
         }
         return ch;
      }