var hexDigits = new Array
        ("0","1","2","3","4","5","6","7","8","9","a","b","c","d","e","f"); 

//Function to convert rgb color to hex format
function rgb2hex(rgb) {
 rgb = rgb.match(/^rgb\((\d+),\s*(\d+),\s*(\d+)\)$/);
 return "#" + hex(rgb[1]) + hex(rgb[2]) + hex(rgb[3]);
}

function hex(x) {
  return isNaN(x) ? "00" : hexDigits[(x - x % 16) / 16] + hexDigits[x % 16];
 }

function rgb2hex(rgb) {
    rgb = rgb.match(/^rgb\((\d+),\s*(\d+),\s*(\d+)\)$/);
    function hex(x) {
        return ("0" + parseInt(x).toString(16)).slice(-2);
    }
    return "#" + hex(rgb[1]) + hex(rgb[2]) + hex(rgb[3]);
}

一些浏览器已经返回十六进制的颜色（自Internet Explorer 8及更低版本开始）。如果需要处理这些情况，只需在函数内附加一个条件，例如@gfrobenius建议：

function rgb2hex(rgb) {
    if (/^#[0-9A-F]{6}$/i.test(rgb)) return rgb;

    rgb = rgb.match(/^rgb\((\d+),\s*(\d+),\s*(\d+)\)$/);
    function hex(x) {
        return ("0" + parseInt(x).toString(16)).slice(-2);
    }
    return "#" + hex(rgb[1]) + hex(rgb[2]) + hex(rgb[3]);
}